The orbital chemical shift of N.M.R., which measures the weight of non-s states in the chemical bond, can be related directly to the ionicity for tellurium compounds. In a molecular picture of the solid neglecting d states, the shift is a parabolic function of the number of p-electrons in the valence band. This number depends simply on the ionicity for tellurium bonds and can be modified by change in the local symmetry, especially by amorphization.
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Willig et al. (1977) studied this question.
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