The first side-on bound metal complex of diazene, HNNH | Synapse

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum CenterOriginal Research · 2003 · 1,432 citations
2Reduction of N2 to Ammonia and Hydrazine Utilizing H2 as the ReductantOriginal Research · 2005 · 105 citations
3Exchange of dinitrogen between iron and molybdenum centers and the reduction of dinitrogen bound to iron: implications for the chemistry of nitrogenasesOriginal Research · 1991 · 101 citations
4Catalytic Reduction of Hydrazine to Ammonia with MoFe<sub>3</sub>S<sub>4</sub>−Polycarboxylate Clusters. Possible Relevance Regarding the Function of the Molybdenum-Coordinated Homocitrate in NitrogenaseOriginal Research · 1996 · 113 citations
5Syntheses, Structures and Reactivity of Electron‐Rich Fe and Ru Complexes with the New Pentadentate Ligand Et2NpyS4−H2 {4‐(Diethylamino)2,6‐bis[(2‐mercaptophenyl)thiomethyl]pyridine}Original Research · 2004 · 29 citations

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Übergangsmetallkomplexe mit Schwefelliganden, CI*. Synthese und Struktur von N2H5[Fe(N2H4)(S2C6H4)2] · 1,33N2H4 / Transition Metal Complexes with Sulfur Ligands, Cl*. Synthesis and Structure of N2H5[Fe(N2H4)(S2C6H4)2] · 1,33N2H41994
Transition-metal complexes with sulfur ligands. 88. Dependence of spin state, structure, and reactivity of [FeII(L) ('NH)S4')] complexes on the coligand L (L = CO, N2H2, N2H4, NH3, pyridine, NHCH3NH2, CH3OH, THF, P(OCH3)3, P(OPh)3): model complexes for iron nitrogenases ('NHS4'2-dianion of 2,2'-bis[(2-mercaptophenyl)thio]diethylamine)1992
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