The uptake of carbon dioxide was studied in porous organic solid, p-tert-butylcalix[4]dihydroquinone, in which all calixarenes are self-assembled in a tubular fashion via strong hydrogen bonds. the BET surface area of porous material was found to be 230 m2/g. This represents another rare example in which purely organic crystals can be designed to store and separate gas mixtures.
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Thallapally et al. (2007) studied this question.
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