Cooperation of soft and hard bridging ligands (μ-S and μ-O, respectively) is crucial to the mechanism of heterolytic dihydrogen activation by germanium–ruthenium complex 1 to give syn and anti isomers of the corresponding hydroxogermanium–hydridoruthenium complex 2 (see scheme; dep=2,6-diethylphenyl).
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Matsumoto et al. (2008) studied this question.
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