Light Scattering Study of Rigid, Rodlike Organometallic Block Copolymer Micelles in Dilute Solution

The block copolymer poly(ferrocenyldimethylsilane- b -dimethylsiloxane) (PFS 40 - b -PDMS 480, where the subscripts refer to the mean degree of polymerization) self-assembles in n -decane at 25 °C to form long rodlike micelles (Raez et al. J. Am. Chem. Soc . 2002, 124, 10381). Here, we describe a combination of static (SLS) and dynamic (DLS) light scattering measurements on solutions of the micelles in n -decane. By SLS, we find that the micelles are thin, rigid, rodlike structures with a mean length of ∼960 nm in the limit of zero concentration and a length that increases with concentration. Through a combination of SLS and DLS measurements, we find that that the cross-sectional hydrodynamic diameter of the micelle is 18 nm. These self-assembled structures also appear to have a narrow distribution of lengths (with M w / M n ≈ 1.1). These structures are much smaller than those observed on transmission electron microscopy (TEM) grids obtained from solutions of these self-assembled structures.