Controlled oxidation of palladium nanoparticles provided high‐valent Pd IV oxo‐clusters which efficiently promote directed C−H halogenation reactions. In addition, palladium nanoparticles can undergo changes in oxidation states to provide both high‐valent Pd IV and low‐valent Pd 0 species within one system, and thus a tandem reaction of C−H halogenation and cross‐coupling (C−N, C−C, and C−S bond formation) was successfully established.
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Kim et al. (2017) studied this question.
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