No CO-operation: Two single-site ruthenium complexes, based on a tetradentate ligand, despite structural similarities, display a remarkable difference in their catalytic and chemical behavior (see picture). The fact that the CO-containing complex is formed in the catalytic oxidation of water suggests a novel pathway for the deactivation of ruthenium-based catalysts.
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Kärkäs et al. (2013) studied this question.
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