Matrix ENDOR lines of protons associated with trapped electrons in γ-irradiated glassy matrices of 10M NaOH, methanol and 2-methyltetrahydrofuran at 77°K have been observed. By analysis of the matrix ENDOR line shapes under comparable experimental conditions the linewidth has been related to the spatial extent of the ground state wavefunction of the trapped electron. These experimental results are compared with predictions of the semicontinuum model for trapped electrons and found to be in good agreement.
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Helbert et al. (1972) studied this question.
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