Dynamical Phase Transitions and Cation Orientation-Dependent Photoconductivity in CH(NH₂)₂PbBr₃

The choice of organic cation in hybrid perovskites has large implications for optoelectronic properties, material stability, and crystal structure. In particular, formamidinium ((CH(NH 2 ) 2 + ) perovskites exhibit unusual temperature-dependent trends in photoluminescence, dielectric constant, and phase behavior that are hypothesized to relate to CH(NH 2 ) 2 + reorientations. This contribution describes five distinct, temperature-dependent phase transitions in CH(NH 2 ) 2 PbBr 3 that produce changes in the steady-state photocurrent. Three of these phase transitions do not resolve crystallographically and relate to the orientation and dynamics of CH(NH 2 ) 2 + . These crystallographically unresolvable phase transitions resemble ferroelastic transitions with the formation of nanoscale domains, which we hypothesize are mediated by the strain exerted from geometric frustration of CH(NH 2 ) 2 + quadrupoles. This work demonstrates the importance of cation orientation and dynamics, domain behavior, and their interdependence in the steady-state optoelectronic properties of hybrid perovskites.