o -Phenylene-bridged Me 3 Cp/amido titanium complexes have been prepared via the Suzuki coupling reaction. Some of them show reactivity comparable to that of the CGC [Me 2 Si(η 5 -Me 4 Cp)(N t Bu)]TiCl 2 in ethylene/1-hexene copolymerization in terms of activity, molecular weight, and comonomer incorporation.
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Cho et al. (2006) studied this question.
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