Structural differences between two crystal modifications of poly(γ‐benzyl L‐glutamate)

X‐ray diffraction patterns were obtained for as‐cast and oriented films of poly(γ‐benzyl L ‐glutamate) and a comparison was made of the molecular packing of the α‐helices in forms B and C . Form B snowed Bragg reflections on the layer lines as well as on the equator. The spacings were explained by a monoclinic unit cell comprising two chains, with a = 29.0 6 Å, b = 13 2 0 Å, c = 27.2 7 Å α = γ = 90°. and β = 96°. The chains contained in this unit cell and consequently alternating in the crystal have opposite chain directions. Form C showed continuous scattering on the layer lines and reflections on the equator. This form, therefore, is a nematiclike paracrystal in which the packing of α‐helices is periodic in the direction lateral to the chain axis ( a = 14.8–115.2 Å, b = 14.3–14.8 Å, c = 27 Å, and γ = 118°–120°), but the relative levels of the chains along the chain axes are displaced. The formation of form C may be attributed to random placement of two chains with mutually opposite chain directions.