Answers are grounded in this paper and cite their sources.
CF3 on C: Trifluoromethylation of allylsilane derivatives was accomplished through the use of CuI and Togni's reagent (1) under mild conditions. The reaction of allylsilanes without a substituent in the 2-position gave vinylsilane derivatives, while 2-substituted allylsilanes afforded desilylated products. The utility of the products was demonstrated through their further transformation.
No takes yet. Share an insight, caveat, or question.
Shimizu et al. (2012) studied this question.
Synapse has enriched 5 related papers. Consider them for comparative context: