Zeolites with embedded bismuth compounds display strong, air-stable, long-lived, ultrabroadband, and tunable near-infrared photoluminescence (see picture). Bismuth ions not only act as luminescence-active centers, but also as blocks for selectively closing the “in–out windows” of water molecules. Bismuth active centers can be sealed in a low-vibrational environment by bismuth agglomerates even when the sample still contains a large amount of water.
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Sun et al. (2009) studied this question.
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