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Experimental study demonstrates photo-induced aqueous aldol condensation of biomass carbonyls using dual-ligand quantum dots, highlighting molecular designs for semiconductor photocatalysts.
CdS QDs were fabricated using bi-ligands 11-sulfanylundecanoic acid and proline for photo-induced aqueous-phase aldol condensation of biomass-derived furfural compounds and ketones, and they displayed acceptable selectivity, activity and recycling properties for generation of a wide range of products with diverse applications. This work facilitates understanding the molecular-level design concepts of semiconductor photocatalysts.
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Wei et al. (2023) studied this question.
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