The infrared spectrum of a sunspot is analyzed in the L -band region 3.1-4.0 μm (2497-3195 cm -1 ) and 2.02-2.35 μm (4251-4962 cm -1 ) in the K band. A new laboratory emission spectrum covering 2500- 6000 cm -1 is analyzed to help make the assignments. Quantum number assignments are made using linelists computed using variational calculations, assisted by tabulations of experimental energy levels. There are 1207 new H 2 16 O lines assigned in the L band and 508 new lines in the K band. Vibrational band origins of 11242.8 ± 0.1 cm -1 and 12586 ± 1 cm -1 are obtained for the (051) and (061) states.
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Zobov et al. (2000) studied this question.
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