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1,3‐Dimetallaallenes 1 or carbyne complexes 2 are the simplest examples of compounds in which different transition metal complex fragments or units of main group elements are terminally bound to C n bridges. Polymers such as 3 with C 4 bridges which link d 8 ML 2 building blocks are of particular interest as materials with novel properties. equation image
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Heinrich Lang (1994) studied this question.
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