We present a resonance Raman investigation of the lowest energy dipole-allowed absorption band of [Au 2 (dcpm) 2 ](ClO 4 ) 2 (dcpm = bis(dicyclohexylphosphine)methane). The resonance Raman spectra provide the first experimental proof of the 5dσ* → 6pσ electronic transition in dinuclear gold(I)−phosphine compounds. A resonance Raman intensity analysis of the spectra allows estimation of the structural changes of the [dσ*pσ] excited states relative to the ground state.
No takes yet. Share an insight, caveat, or question.
Leung et al. (1999) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: