The photopolymerization ability of photosensitized alkoxyamines has been investigated. These compounds behave as interesting two‐component photoinitiators. Laser flash photolysis, electron spin resonance, and density functional theory allow to support the interactions encountered between the photosensitizer (benzophenone and isopropylthioxanthone) and the alkoxyamines (CO bond breaking and hydrogen transfer) and the side reactions of the nitroxide radical with photosensitizer (electron transfer).
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Versace et al. (2010) studied this question.
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