It was predicted by us [J. Chem. Phys. 114, 4912 (2001)] that the presence of local density enhancements in a neat supercritical fluid near its liquid–vapor critical point should generate a weak anomaly in the fluid's self-diffusion constant. Herein, we examine possible reasons why the limited number of experimental studies conducted to date on diffusion constants in near-critical supercritical fluids do not provide clear evidence of this predicted weak anomaly.
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Drozdov et al. (2002) studied this question.
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