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The ternary A I B III C VI 2 chalcopyrite semiconductors are current of technological interest since they show promise for applications in such areas as solar cells and non‐linear optics. In this paper we give a survey about the crystal chemistry of this compounds including the structure of epitaxial layers and discuss some new results concerning their thermal properties. Furthermore the influence of the p‐d hybridization of the uppermost valence band on the band gap and the nature of the intrinsic defects in CuInSe 2 are considered.
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Kühn et al. (1987) studied this question.
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