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Control of the coupling selectivity (regioselectivity) in the horseradish peroxidase-catalyzed oxidative polymerization of 4-substituted phenols has been achieved by changing the hydrophobic parameters of the monomer substituent and organic solvent (π and logP, respectively), yielding soluble polyphenols with a different ratio of phenylene/oxyphenylene units.
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Mita et al. (2002) studied this question.
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