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The kinetics of spontaneous copolymerization of 1.2‐dimethoxyethylene and p ‐dioxene with maleic anhydride were studied and found to obey the following relation: These results were explained by regarding the charge‐transfer complex between ethers and maleic anhydride as a single monomer and assuming the participation of the charge‐transfer complex in both the initiation and propagation steps. The activation energies of thermal (spontaneous) polymerization were calculated for the p ‐dioxene‐maleic anhydride system as follows:
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Kokubo et al. (1969) studied this question.
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