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June 1, 1993Angewandte Chemie International Edition in English

CH Bond Addition to a VNR Bond: Hydrocarbon Activation by a Sterically Crowded Vanadium System

Jan de With Andrew D. Horton

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Abstract

Alkanes, alkenes, and benzene are activated by intermediate 1, which has a three-coordinate vanadium center, by the addition of a CH bond to one of the VN bonds. The unstable complex 1 is generated from [RNV(NHR)2R′] on thermolysis. R = tBu3Si.

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With et al. (1993) studied this question.

synapsesocial.com/papers/6a70efc7f44fa9f079deaeb1 https://doi.org/10.1002/anie.199309031

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