Acyclic diene metathesis (ADMET) polymerization is a unique strategy for achieving polymers with precise control over the primary structure. This precision is obtained by specific monomer design and carefully controlled polymerization conditions. Over time, this approach has produced an array of sophisticated architectures ranging from precise polyethylenes, to hyperbranched polymers, to rotaxanes.
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Schulz et al. (2014) studied this question.
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