The combination of attractive supramolecular interactions of a hydrophobic Au I -metallopeptide with the shielding effect of flexible oligoethylene glycol chains provides access to a stepwise self-assembly of a Au I -metalloamphiphile in water. Kinetic control of the supramolecular polymer morphology is achieved using a temperature-dependent assembly protocol, which yields low dispersity supramolecular polymers (metastable state I) or helical bundled nanorods (state II).
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Kemper et al. (2017) studied this question.
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