Spectral variability of sea surface skylight reflectance and its effect on ocean color

In this study, sea surface skylight spectral reflectance ρ(λ) was retrieved by means of the non-linear spectral optimization method and a bio-optical model. The spectral variability of ρ(λ) was found to be mainly influenced by the uniformity of the incident skylight, and a model is proposed to predict the ρ(λ) spectral dependency based on skylight reflectance at 750 nm. It is demonstrated that using the spectrally variable ρ(λ), rather than a constant, yields an improved agreement between the above-water remote sensing reflectance R(rs)(λ) estimates and concurrent profiling ones. The findings of this study highlight the necessity to re-process the relevant historical above-water data and update ocean color retrieval algorithms accordingly.