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Weak ferromagnetic [Cu ₃ (dmMePEA) ₃ (μ ₃ -CO ₃ )(ClO ₄ ) ₃ ]ClO ₄ ( 1 ) and strong antiferromagnetic [Cu ₂ (iptren) ₂ (μ ₂ -CO ₃ )](ClO ₄ ) ₂ ·H ₂ O ( 2 ) carbonato-bridged Cu( ii ) complexes were synthesized via atmospheric fixation of CO ₂ in slightly basic solutions.
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Massoud et al. (2015) studied this question.
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