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Two nitro functionalized Cu(II)-MOFs exhibit high CO 2 uptake with nice selectivity over other gases like H 2, N 2, and CH 4, which is potentially important for the removal of carbon dioxide from industrial flue gas and natural gas. Here the selective CO 2 adsorption by these MOFs is primarily due to the presence of suitable voids with −NO 2 group functionalized pore walls in the dehydrated framework, which is unprecedented.
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Maity et al. (2016) studied this question.
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