The first infinite 2D copper(II) complex with alternating “buckets” and upside down “buckets”, which form large cavities through interlayer π−π and C−H- - -OC hydrogen-bonding interactions, was obtained by self-assembly of copper(II) acetate with the 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene (titmb) ligand.
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Liu et al. (1999) studied this question.
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