High‐Performance Non‐Fullerene Organic Solar Cells Based on a Selenium‐Containing Polymer Donor and a Twisted Perylene Bisimide Acceptor

is designed to match with a non-fullerene acceptor (SdiPBI-S). The corresponding solar cells show a high efficiency of 8.22%, which result from synergetic improvements of light harvesting, charge carrier transport and collection, and morphology. The results indicate that rational design of novel donor materials is important for non-fullerene organic solar cells.