Pd-catalyzed coupling reactions have been used to prepare meso-phosphorylporphyrins. A 2D metal-organic network formed via P horizontal lineO...Zn axial supramolecular coordination of 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrin is the first example of a 2D framework based on phosphorylporphyrin derivatives.
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Enakieva et al. (2009) studied this question.
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