contrary to the common belief that a simple description of the bonding in Ni–S(Se) clusters is not possible, the electronic structure of the cluster [Ni5S(StBu)5]− (1) can be understood in terms of an idealized molecular orbital interaction diagram. The more complicated cluster [Ni20Se12(SeMe)10]2− can also be analyzed in this manner.
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Cheung et al. (1997) studied this question.
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