The hydrothermal reaction of Cd(ClO 4 ) 2 ·6H 2 O and Gatifloxacin(Gati) affords a binuclear complex of Gatifloxacin, [Cd(Gati)(py) 3 ] 2 ·(ClO 4 ) 4 ( 1 ), which is characterized by X‐ray crystallographic analysis, IR and fluorescent spectroscopy. Crystal data for 1 , C 34 H 36 CdCl 2 FN 6 O 12 : monoclinic, P 2 1 / c , a = 18.3642(5), b = 12.8156(4), c = 16.7210(5) Å, β = 97.931(1)°, V = 3897.6(2) Å 3 , Z = 4. The local surrounding of the Cd II ion is a slightly distorted octahedron. Solid‐state fluorescence measurements of 1 at room temperature show an emission peak at 439 nm.
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Li et al. (2005) studied this question.
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