October 1, 2003Organic Letters

SmI₂/Water/Amine Mediates Cleavage of Allyl Ether Protected Alcohols: Application in Carbohydrate Synthesis and Mechanistic Considerations

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ADAnders DahlénAstraZeneca (Australia)ASAndreas Sundgren MLMartina LahmannKTH Royal Institute of Technology

Abstract

[reaction: see text]. SmI2/H2O/amine provides selective cleavage of unsubstituted allyl ethers in good to excellent yields. This method is therefore useful in deprotection of alcohols and carbohydrates.

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Dahlén et al. (2003) studied this question.

synapsesocial.com/papers/6a715b2cfebe604dd70a0757 https://doi.org/10.1021/ol0354831

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SmI₂/Water/Amine Mediates Cleavage of Allyl Ether Protected Alcohols: Application in Carbohydrate Synthesis and Mechanistic Considerations

Abstract

Discussion

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Cite This Study

SmI₂/Water/Amine Mediates Cleavage of Allyl Ether Protected Alcohols: Application in Carbohydrate Synthesis and Mechanistic Considerations

Abstract

Discussion

Member takes

Cite This Study

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