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A hydrophobic MOF, OPA/MIL-125-NH2, whose Ti cluster was alkylated with octadecylphosphonic acid (OPA), was found to enhance photocatalytic H2O2 production in a two-phase system. Its activity exceeded that of linker-alkylated MIL-125-NH2. OPA/MIL-125-NH2 was modified on its outermost surface, which resulted in the activity enhancement while preserving the inner pores of the inherent MOF.
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Kawase et al. (2019) studied this question.
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