Readily accessible dibenzothiophene sulfoximine is an NH 3 surrogate allowing the preparation of free anilines by copper‐catalyzed cross‐coupling reactions with aryl iodides or amides followed by radical S−N bond cleavage. The one‐pot/two‐step reactions sequence leads to the aminated products in good yields.
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Li et al. (2017) studied this question.
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