January 1, 1982Journal of the Chemical Society Chemical Communications

Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex

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Abstract

A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe3)3, undergoes intramolecular hydroacylation to cyclopentanone.

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Cite This Study

David Milstein (1982) studied this question.

synapsesocial.com/papers/6a7176bf31a3df824329a538 https://doi.org/10.1039/c39820001357

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Abstract

A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe3)3, undergoes intramolecular hydroacylation to cyclopentanone.