The effects on Wool Alcohols B.P. of gradual autoxidation during storage at room temperature have been compared with the known effects of accelerated oxidation. There is a decrease in emulsification value, a bleaching of the surface, and, contrary to previous reports, a rapid fall in melting point. Autoxidation, even under bad conditions, has been inhibited, apart from a slight fall in melting point, for at least 23 months by the addition of 500 p.p.m. of butylated hydroxyanisole, but certain other antoxidant systems had only a limited effect.
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Clark et al. (1960) studied this question.
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