Peculiarities of structure formation of layered chalcogenides with mixed tetrahedral and octahedral cation coodination are considered. The criterion for purposive search of new layered compounds was proposed. New layered compounds as Cu(Ag)Ga 2.5 In 2.5 S 8 , Mg 0.5 Ga 2 InS 5 , CuIn 5 S 3 Se 5 and others were obtained and studied.
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Moldovyan et al. (1993) studied this question.