Low voltage and very high efficiency deep-blue phosphorescent organic light-emitting devices

We report on very high efficiency deep-blue phosphorescent organic light-emitting devices (PHOLEDs) based on iridium(III) bis(4′,6′-difluorophenylpyridinato)tetrakis(1-pyrazolyl)borate (FIr6). Dual emissive layers consisting of an N,N′-dicarbazolyl-3,5-benzene layer doped with 4wt% FIr6 and a p-bis(triphenylsilyly)benzene layer doped with 25wt% FIr6 were employed to maximize exciton generation on FIr6 molecules. Combined with the p-i-n device structure, we achieved a low turn-on voltage of 3.2V and very high power efficiencies of 25±2lm∕W at 100cd∕m2 and 20±2lm∕W at 1000cd∕m2 for such deep-blue PHOLEDs with peak emission at a wavelength of 458nm.