Noncovalent interactions are used to generate a polymeric supramolecular chiral catalyst (see picture). This heterogeneous catalyst, which is based on Feringa's MonoPhos/RhI system, is formed by orthogonal self-assembly of recognition motifs through hydrogen bonding and ligand-to-metal coordination interactions. It shows excellent asymmetric induction and reusability in the catalysis of the asymmetric hydrogenation of dehydro-α-amino acid and enamide derivatives.
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Shi et al. (2006) studied this question.
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