A variety of new chiral phosphanes were prepared by highly diastereoselective additions of phosphanes to α,β‐unsaturated carbonyl compounds and related acceptor‐substituted olefins derived from myrtenal as ex chiral pool source. Monophosphanes with astereogenic as well as stereogenic phosphorus are described. In addition diphosphanes were prepared by a highly diastereoselective double conjugate addition of a secondary diphosphane. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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Wiese et al. (2005) studied this question.
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