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Highly stable COF supported Pd(0) and Pd( ii ) nanoparticles ( i.e. Pd(0)@Tppa-1 and Pd(ii)@TpPa-1 ) have been synthesized. Pd(0)@TpPa-1 serves as a robust and efficient heterogeneous catalyst for copper free Sonogashira and Heck coupling reactions under basic conditions, whereas Pd(ii)@TpPa-1 satisfactorily catalyzes intramolecular oxidative biaryl synthesis under acidic conditions.
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Pachfule et al. (2014) studied this question.
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