And the world is your oyster…︁ Sequential halogenation/oxygenation reactions of 2-diisopropylsilylpyrimidine-substituted arenes provide a general and efficient synthesis of substituted meta-halophenols from simple aryl iodides (see scheme; Piv=pivaloyl). The products are poised to undergo diverse CC, CN, and CO bond-forming reactions that enable the transformation of their framework and the introduction of valuable functionalities.
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Sarkar et al. (2013) studied this question.
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