The oxidative addition of acetic or formic acid to Pd0(PPh3)4 in DMF affords a cationic palladium(II) hydride, [trans-HPd(PPh3)2(DMF)]+, with acetate or formate as the counter anion. The two reactions are reversible. The equilibrium and kinetic constants of the oxidative additions have been determined.
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Amatore et al. (2000) studied this question.
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