January 1, 1982Journal of the Chemical Society Chemical Communications

Selective homogeneous catalytic oxidation of olefins using oxygen/hydrogen mixtures: oxygen atom transfer from an iridium hydroperoxide

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Abstract

An iridium (III) hydride complex in solution catalyses the O2-co-oxidation of cyclo-octene and H2 to cyclo-octanone and water, respectively, via a hydroperoxide intermediate.

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Cite This Study

Atlay et al. (1982) studied this question.

synapsesocial.com/papers/6a71cb37febe604dd70a4975 https://doi.org/10.1039/c39820000406

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Abstract

An iridium (III) hydride complex in solution catalyses the O2-co-oxidation of cyclo-octene and H2 to cyclo-octanone and water, respectively, via a hydroperoxide intermediate.