Hierarchical MIL-88B-on-MOF-5 octapods were synthesized via a mechanism involving phase-competition-driven growth (PCDG). Dramatically different morphologies (nanocubes, octapods, flowers) were also produced by controlling the phase competition between MIL-88B and MOF-5. The octapod MOFs showed a high catalytic performance for the reverse water-gas shift (RWGS) reaction.
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Zhang et al. (2019) studied this question.
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