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Palladium(II) 3-iminophosphine derivatives were screened as intermolecular hydroamination catalysts, with (3-iminophosphine)(allyl)palladium triflate determined to be the most active for the hydroamination of 1,3-cyclohexadiene and phenylacetylene. The iminophosphine ligands were synthesized by a three-step process and coordinated in an η 2 and η 1 manner to palladium(II) chloride and (allyl)palladium(II) chloride, respectively.
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Shaffer et al. (2008) studied this question.
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