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The title compound, C10H13ClN2O3S, known as chlorpropamide, was crystallized from a heptane–ethyl acetate solution in a new polymorphic form. The conformations of molecules and their packing in the new polymorph differ significantly from those in the previously reported structure, although the intermolecular hydrogen-bond patterns in both polymorphs are very similar.
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Drebushchak et al. (2006) studied this question.
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