Qualitative chemical information is used as a guideline for correlations between equilibrium constants or between equilibrium constants and atomic charges (deduced from quantum mechanics calculations). Pa(V) and Nb(V) hydrolysis constants are also recalculated from experimental data. log K 1 ° ( A n IV / R O 2 2 − ) = 6.5 9 ± 0.5 5 ( S 2 O 3 2 − ) , 10.0 6 ± 0.8 8 ( S O 3 2 − ) , 11.9 7 ± 1.0 7 ( C O 3 2 − ) , and 10.0 5 ± 0.8 8 ( HP O 4 2 − ) are estimated based on the trend of affinity for An cations in the series C O 3 2 − > HP O 4 2 − ≈ S O 3 2 − > S O 4 2 − ≈ S 2 O 3 2 − . These ideas and values are used to discuss U(IV) chemistry in S-containing ground-waters.
No takes yet. Share an insight, caveat, or question.
Vitorge et al. (2007) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: